The rate and extent to which chemical reactions occur



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Tempertaure


Tempertaure
Temperature is a physical quantity that expresses hot and cold. It is the manifestation of thermal energy, present in all matter, which is the source of the occurrence of heat, a flow of energy, when a body is in contact with another that is colder or hotter.
Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have used various reference points and thermometric substances for definition. The most common scales are the Celsius scale (formerly called centigrade, denoted as °C), the Fahrenheit scale (denoted as °F), and the Kelvin scale (denoted as K), the last of which is predominantly used for scientific purposes by conventions of the International System of Units (SI).
The lowest theoretical temperature is absolute zero, at which no more thermal energy can be extracted from a body. Experimentally, it can only be approached very closely (100 pK), but not reached, which is recognized in the third law of thermodynamics.
Temperature is important in all fields of natural science, including physics, chemistry, Earth science, astronomy, medicine, biology, ecology, material science, metallurgy, mechanical engineering and geography as well as most aspects of daily life.
Effects

  • Many physical processes are related to temperature, some of them are given below:

  • the physical properties of materials including the phase (solid, liquid, gaseous or plasma), density, solubility, vapor pressure, electrical conductivity, hardness, wear resistance, thermal conductivity, corrosion resistance, strength

  • the rate and extent to which chemical reactions occur

  • the amount and properties of thermal radiation emitted from the surface of an object

  • the speed of sound which is a function of the square root of the absolute temperature.

Scales
Temperature scales differ in two ways: the point chosen as zero degrees and the magnitudes of incremental units or degrees on the scale.

Commonly used scales



The Celsius scale (°C) is used for common temperature measurements in most of the world. It is an empirical scale that was developed by historical progress, which led to its zero points 0 °C being defined by the freezing point of water, and additional degrees defined so that 100 °C was the boiling point of water, both at sea-level atmospheric pressure. Because of the 100-degree interval, it was called a centigrade scale. Since the standardization of the kelvin in the International System of Units, it has subsequently been redefined in terms of the equivalent fixing points on the Kelvin scale, and so that a temperature increment of one degree Celsius is the same as an increment of one kelvin, though they differ by an additive offset of approximately 273.15.
The United States commonly uses the Fahrenheit scale, on which water freezes at 32 °F and boils at 212 °F at sea-level atmospheric pressure.

Absolute zero



At the absolute zero of temperature, no energy can be removed from matter as heat, a fact expressed in the third law of thermodynamics. At this temperature, matter contains no macroscopic thermal energy, but still has quantum-mechanical zero-point energy as predicted by the uncertainty principle, although this does not enter into the definition of absolute temperature. Experimentally, absolute zero can be approached only very closely; it can never be reached (least temperature attained by experiment is 100 pK). Theoretically, in a body at absolute zero temperature, all classical motion of its particles has ceased and they are at complete rest in this classical sense. The absolute zero, defined as 0 K, is approximately equal to −273.15 °C, or −459.67 °F.

Absolute scales



Referring to the Boltzmann constant, to the Maxwell–Boltzmann distribution, and to the Boltzmann statistical mechanical definition of entropy, as distinct from the Gibbs definition,[4] for independently moving microscopic particles, disregarding interparticle potential energy, by international agreement, a temperature scale is defined and said to be absolute because it is independent of the characteristics of particular thermometric substances and thermometer mechanisms. Apart from the absolute zero, it does not have a reference temperature. It is known as the Kelvin scale, widely used in science and technology. The kelvin (the word is spelled with a lower-case k) is the unit of temperature in the International System of Units (SI). The temperature of a body in its own state of thermodynamic equilibrium is always positive, relative to the absolute zero.
Besides the internationally agreed Kelvin scale, there is also a thermodynamic temperature scale, invented by Lord Kelvin, also with its numerical zero at the absolute zero of temperature, but directly relating to purely macroscopic thermodynamic concepts, including the macroscopic entropy, though microscopically referable to the Gibbs statistical mechanical definition of entropy for the canonical ensemble, that takes interparticle potential energy into account, as well as independent particle motion so that it can account for measurements of temperatures near absolute zero. This scale has a reference temperature at the triple point of water, the numerical value of which is defined by measurements using the aforementioned internationally agreed Kelvin scale.

International Kelvin scale



Many scientific measurements use the Kelvin temperature scale (unit symbol: K), named in honor of the physicist who first defined it. It is an absolute scale. Its numerical zero point, 0 K, is at the absolute zero of temperature. Since May, 2019, its degrees have been defined through particle kinetic theory, and statistical mechanics. In the International System of Units (SI), the magnitude of the kelvin is defined through various empirical measurements of the average kinetic energies of microscopic particles. It is numerically evaluated in terms of the Boltzmann constant, the value of which is defined as fixed by international convention.

Statistical mechanical versus thermodynamic temperature scales


Since May 2019, the magnitude of the kelvin is defined in relation to microscopic phenomena, characterized in terms of statistical mechanics. Previously, since 1954, the International System of Units defined a scale and unit for the kelvin as a thermodynamic temperature, by using the reliably reproducible temperature of the triple point of water as a second reference point, the first reference point being 0 K at absolute zero.
Historically, the triple point temperature of the water was defined as exactly 273.16 units of the measurement increment. Today it is an empirically measured quantity. The freezing point of water at sea-level atmospheric pressure occurs at approximately 273.15 K = 0 °C.


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