Jip 4 At-sea monitoring of surface dispersant effectiveness



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raw fluor

escence units

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1m depth on 05/23/2010

natural

dispersion



background

chemical


dispersion

10 min.


post spray

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sampling


transect

Pre-application

Post-application

sampling


vessel

untreated

oil

dispersed



oil

coordinates

oil drift

coordinates

sampling

vessel


not be easy in such circumstances, carrying out Tier II and Tier III fluorometry monitoring where it

is possible can provide useful qualitative evidence of the environmental benefit of dispersant use,

as demonstrated at the Sea Empress incident (Lunel et al., 1996). 

Tier III: additional monitoring

Tier III uses the same methodology as Tier II, but with sampling occurring at additional depths to

further define the shape and size of the dispersed oil cloud/plume. This is achieved by either

taking additional readings to a depth of 10 metres in areas along the transect where there was a

peak in readings at 1 metre, or by running the transect with fluorometers deployed at two different

IPIECA-IOGP Oil Spill Response Joint Industry Project

12

When taking fluorometry



readings, a transect

should be followed

through the slick: if there

is an increase in readings

of five times between the

untreated oil (left) and the

dispersed oil (right), the

dispersant may be

considered as effective.

Figure 3  Monitoring the effectiveness of dispersant using fluorometry

Sour


ce: US Coast Guar

d

Figure 4  Example result from fluorometer monitoring of a vessel dispersant application test to



evaluate effectiveness

Sour


ce: NOAA


depths (for example, at 1 metre and 5 metres). Tier III monitoring may also include the

measurement of the physical and chemical parameters of the water column, including

temperature, dissolved oxygen, pH, turbidity, conductivity (surrogate for salinity), and any other

parameters which may have an effect on the rate of dispersion.

Field Guides on dispersant application monitoring have been produced by OSRL, based on the

SMART Protocol. These are freely available at: 

http://www.oilspillresponse.com/technical-

development/technical-field-guides

.

Monitoring prolonged dispersant application



There may be circumstances where the surface application of dispersant is feasible and required

for prolonged periods. Scenarios may arise involving ongoing oil releases from sources such as

vessels, subsea pipelines or offshore platforms. This issue has been considered by the US

National Response Team, and led to the publication of guidance for the monitoring of dispersant

operations that are expected to exceed four days. The guidance supplements, but does not

replace, the SMART protocol.

Prolonged monitoring addresses estimations of the weathering characteristics and potential

dispersibility of oil. In some cases these studies may have been undertaken as part of the

contingency planning process, and relevant information would therefore be available to response

managers at the commencement of an incident. Where this is not the case, it may be possible to

undertake rapid laboratory analyses of the spilled oil to ascertain weathering characteristics

(particularly increases in viscosity and emulsification) and how these may reduce the effectiveness

of the dispersant. Such laboratory information can be verified in the field as the response

progresses, by carefully-controlled and observed test spraying from vessels in the field on ageing

areas of the spilled oil—assuming such areas remain and have not been prevented by the success

of the response. The test sprays can be monitored with visual observation and fluorometry, and

correlated with laboratory testing and, possibly, also with a shipboard field effectiveness test.

One outcome of these various tests will be a better understanding of dispersant effectiveness in

terms of the cut-off point for its application during prolonged operations. This will provide field

operational teams with a heightened awareness of the likely success of ongoing operations, and

of where particular attention may need to be given to ensure that dispersant operations remain

effective, e.g. by recognizing the appearance of oil that is becoming non-dispersible, and the

geographic areas where operations are unlikely to be viable.

13

At-sea monitoring of surface dispersant effectiveness




All aspects of the potential use of dispersants require planning, which should include provision for

mobilizing the appropriate resources for dispersant effectiveness monitoring. The emergency

response phase (typically the initial few hours of an incident) is focused on Tier I SMART

monitoring. More detailed monitoring capability associated with Tier II and Tier III monitoring is

most likely to be held and deployed by specialized oil spill response organizations with dedicated

dispersant application capability. 

Equipment

Tier I monitoring equipment may be limited to ensuring the availability of resources, guidelines and

procedures for the observation of oil and the appearance of dispersed oil. Digital camera(s) and

video recorder(s), geo-referenced where possible, and in a ready-to-go condition, should be

available to record observations. Camera systems mounted on aerostats are increasingly being

used by oil spill response vessels. Unmanned aerial vehicles (UAVs) may also be available to

responders. These aerial platforms may carry both visual and IR imaging.

Where practical, and if considered necessary, an organization may maintain simple field

effectiveness testing kits as part of the first-response equipment. More sophisticated monitoring

tools such aerial remote sensing capability and fluorometry are likely to be held and deployed by

specialized oil spill response organizations and scientific institutes.

Response managers and decision makers are likely to request rapid communication of the initial

results of dispersant test sprays. This may extend to requirements for live image feeds and voice

communications from field supervisors and vessel/aerial-based observers to the Command centre. 

Personnel

It is vital for first responders involved in supervising or observing test sprays or initial dispersant

operations to be familiar with the required techniques for observation and verification of dispersant

effectiveness.

Training personnel for this role can be challenging, considering that the opportunities for real-time

observation and monitoring of dispersant application are opportunistic and very limited.

Supporting materials have been developed which assist with the correct implementation of

protocols, including the following examples available from NOAA:

http://response.restoration.noaa.gov/oil-and-chemical-spills/oil-spills/resources/dispersant-

application-observer-job-aid.html

http://response.restoration.noaa.gov/training-and-education/training/workshops/aerial-

observation-training.html 

IPIECA-IOGP Oil Spill Response Joint Industry Project

14

Planning considerations




Personnel from specialized oil spill response organizations will be expected to have undergone

appropriate training and development as part of their organization’s internal training programmes,

and to be competent to undertake monitoring associated with the dispersant capability mobilized

by their organizations.

It is recommended that the team undertaking monitoring includes representation from relevant

authorities, agencies or regulators. This is to ensure that consensus on observations can be

reached in the field and, where there is uncertainty about effectiveness, this can be raised and

further monitoring undertaken to provide further data.

Operational support and logistics

All monitoring will require some degree of logistical support, and in all cases the basic transport of

observers by vessel or aircraft to the site will be required. If spraying is from a vessel it may be

possible for the observation to take place from the same vessel. At some larger spills there are

likely to be demands from various at-sea response operations for vessels and aircraft. It is

imperative that monitoring activities are highlighted in advance through contingency planning. The

incident management team should therefore be prepared to integrate monitoring requirements

into the response effort and allocate adequate resources.

In many spill scenarios, vessels of opportunity (VOOs) can be used to support more advanced

Tier II and Tier III monitoring. Operationally, the vessels need to be able to manoeuvre at slow

speeds, tow fluorometers (which are typically towed at speeds up to 2 knots), and be sufficiently

manoeuvrable to navigate the required path through the slick. A VOO also needs to be able to

travel quickly between deployments to different slicks or operating bases as required. 

Practically, a VOO needs to have sufficient deck space and the means of securing a davit, if

required, to deploy the fluorometer. Vessels with high sides will be difficult to work from due to the

limitations in easily deploying and recovering the submersible equipment. Finally, dependent upon

the location and type of the incident and the ongoing operations, suitable and sufficient

accommodation may be required for the monitoring team. 

The short operational time horizons between vessel-borne spraying operations are compounded

when aircraft are used to spray dispersant because, for safety reasons, the vessel is required to

move off-station during the aerial spray operation and then return to the treated area on

completion. While aerial dispersant spraying can prove extremely effective, attempting to

establish numerical efficacy using vessel-borne equipment following an aerial spray operation

can be fraught with difficulty.

15

At-sea monitoring of surface dispersant effectiveness




The application of dispersants to floating oil slicks is one of the key at-sea response tools with the potential

to reduce the overall ecological and socio-environmental damages caused by a spill.

However, dispersants are not effective on all oils in all conditions; their effectiveness will vary depending on

the prevailing environmental conditions, and the type of spilled oil and its weathering state. In all cases

following shipping spills, the effectiveness will reduce with time, and there will usually be a ‘window of

opportunity’ for the effective application of dispersant. This does not of course apply in the case of an

ongoing release of oil from an offshore platform where fresh oil, which is amenable to dispersal, continues

to be released over time.

It is important to ensure that dispersant is only used on spilled oil in areas where this is appropriate and

when there is a reasonable expectation of it being effective. Monitoring should be established to verify that

the dispersant is effective. Initial estimations of likely effectiveness may be based on studying an oil’s

properties (notably the viscosity and pour point) and on computer modelling predictions of the oil’s fate, or, in

cases where operations are fixed and the oil type is known, on laboratory studies of oil weathering and

dispersibility. It should be recognized that the behaviour of oil at sea means that estimations may not match

the reality, and some weathering processes, such as emulsification, are difficult to predict accurately.

It is typical for national regulations to include laboratory testing of dispersant effectiveness prior to a product

being allowed for use; this is explained in detail in the IPIECA-IOGP document, Guidelines on oil characterization

to inform spill response decisions (IPIECA-IOGP, 2013). These tests provide the means to screen out poor

products, but they cannot reproduce open sea conditions. The results of such laboratory testing (usually

presented as ‘percentage effectiveness’) cannot, therefore, be extrapolated to likely performance in the field.

The difficulties of calculating both the volume of floating oil slicks and the extent of oil naturally or chemically

dispersed beneath a slick mean that it is not currently possible to quantify with any degree of precision the

effectiveness of dispersant applied in the field. Monitoring effectiveness is therefore a qualitative exercise, which

focuses on determining whether the application of dispersant has led to increased levels of dispersed oil

coupled, where possible, with observations of a reduced area of surface slick.

The use of field effectiveness tests coupled with initial test sprays can help decision makers to determine

whether the full deployment of dispersant should go ahead. However, such tests need to be undertaken

quickly so as to avoid unnecessary delays in the decision making process.

The SMART protocol provides a suitable approach for practical monitoring of effectiveness in the field. In

many cases monitoring will be limited to visual observations from vessel or aircraft, possibly supported by

remote sensing. In larger spills it may be viable to utilize in-water monitoring using fluorometry, although this

is difficult to deploy in relation to aerial dispersant application. In larger incidents where the primary

application is aerial, limited application of dispersant by vessels may also be carried out to enable in-water

monitoring to be undertaken.

In all cases the monitoring should include representations from relevant authorities and be carried out on a

regular basis to ensure that the dispersant remains effective on weathering oil.

IPIECA-IOGP Oil Spill Response Joint Industry Project

16

Conclusions and recommendations




AMSA (2012). National Plan Oil Spill Dispersant Effectiveness Field Test Kit (Nat-DET): Operational

Guide. Revision: June 2012. Australian Maritime Safety Authority (AMSA).

http://www.amsa.gov.au/forms-and-publications/Publications/NatDET_Guide_2012.pdf

BenKinney, M., Pascal, B., Huler, C., Wood, B., Russell, M., Nevin, A. and Gass, M. (2011).

Getting SMARTer: Recommendations for Improving SMART Monitoring Procedures Based on

Experiences from the Deepwater Horizon Response: Scientific Support for Deepwater Horizon

(DWH) Aerial Dispersant Operations. In International Oil Spill Conference Proceedings, March

2011, Vol. 2011, No. 1, pp. abs349. 2011.

http://dx.doi.org/10.7901/2169-3358-2011-1-349

Fingas, M. F., Kyle, D. A., Laroche, N. D., Fieldhouse, B. G., Sergy, G. and Stoodley, R. G.

(1995). The effectiveness testing of oil spill-treating agents. In The Use of Chemicals in Oil Spill



Response, ASTM STP1252, P. Lane (Ed.). ASTM International, Philadelphia, PA, USA. pp. 286-

298. 


www.astm.org/DIGITAL_LIBRARY/STP/SOURCE_PAGES/STP1252.htm

IPIECA-IOGP (2013). Finding 19: Guidelines on oil characterization to inform spill response



decisions. Finding 6 of the IOGP Global Industry Response Group (GIRG) response to the

Deepwater Horizon incident in the Gulf of Mexico in April 2010. IPIECA-IOGP Oil Spill Response

Joint Industry Project (OSR-JIP). 

http://oilspillresponseproject.org/completed-products

IPIECA-IOGP (2015). Net environmental benefit analysis (NEBA). IPIECA-IOGP Good Practice

Guide Series, Oil Spill Response Joint Industry Project (OSR-JIP). IOGP Report 517.

http://oilspillresponseproject.org/completed-products

IPIECA-IOGP (2015a). Dispersants: surface application. IPIECA-IOGP Good Practice Guide

Series, Oil Spill Response Joint Industry Project (OSR-JIP). IOGP Report 532.

http://oilspillresponseproject.org/completed-products

Lunel T., Swannell R., Rusin J., Bailey N., Halliwell C., Davies L., Sommerville M., Dobie A.,

Mitchel D., McDonagh M. and Lee, K. (1996). Monitoring of the effectiveness of response options

during the Sea Empress incident: a key component of the successful counter-pollution response.

In Spill Science & Technology Bulletin, Vol. 2, Issues 2–3, 1995, pp. 99-112. (Published in 1996.)

www.sciencedirect.com/science/article/pii/S1353256196000114

NRC (1989). Using Oil Spill Dispersants on the Sea. Committee on Effectiveness of Oil Spill

Dispersants, US National Research Council (NRC). National Academy Press, Washington, D.C.

http://www.nap.edu/openbook.php?record_id=736&page=R1

NRC (2005). Oil Spill Dispersants: Efficacy and Effects. Committee on Understanding Oil Spill

Dispersants, US National Research Council (NRC). National Academy Press, Washington, D.C.

http://www.nap.edu/openbook.php?record_id=11283

17

At-sea monitoring of surface dispersant effectiveness



References and further reading


NRT (2013). Environmental Monitoring for Atypical Dispersant Operations, Including Guidance for:

Subsea Application; Prolonged Surface Application. U.S. National Response Team (NRT).

www.nrt.org/production/NRT/NRTWeb.nsf/AllAttachmentsByTitle/SA-1086NRT_Atypical_

Dispersant_Guidance_Final_5-30-2013.pdf/$File/NRT_Atypical_Dispersant_Guidance_Final_5-30-

2013.pdf?OpenElement

Oil Spill Response Limited, Technical Field Guides for Dispersant Application Monitoring.

www.oilspillresponse.com/technical-development/technical-field-guides

.

S. L. Ross (2008). Updating the U.S. SMART Dispersant Efficacy Monitoring Protocol. A review of



OHMSETT dispersant effectiveness test results, 2001–07. S. L. Ross Environmental Research

Limited. Prepared for the USCG Research and Development Center, Groton, CT and U.S.

Department of the Interior, Minerals Management Service.

www.slross.com/publications/AMOP/2009_Updating_the_U.S._SMART_Dispersant_Efficacy_

Monitoring_Protocol.pdf

USCG et al. (2006). Special Monitoring of Applied Response Technologies (SMART). U.S. Coast

Guard (USCG), National Oceanic and Atmospheric Administration (NOAA), U.S. Environmental

Protection Agency (U.S. EPA), Centers for Disease Control and Prevention (CDC), Minerals

Management Service (MMS).

http://response.restoration.noaa.gov/sites/default/files/SMART_protocol.pdf

IPIECA-IOGP Oil Spill Response Joint Industry Project

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© IPIECA-IOGP 2015  All rights reserved.

IOGP represents the upstream oil and gas industry before

international organizations including the International Maritime

Organization, the United Nations Environment Programme (UNEP)

Regional Seas Conventions and other groups under the UN

umbrella. At the regional level, IOGP is the industry representative to

the European Commission and Parliament and the OSPAR

Commission for the North East Atlantic. Equally important is IOGP’s

role in promulgating best practices, particularly in the areas of health,

safety, the environment and social responsibility.

www.iogp.org

IPIECA is the global oil and gas industry association for environmental

and social issues. It develops, shares and promotes good practices and

knowledge to help the industry improve its environmental and social

performance; and is the industry’s principal channel of communication

with the United Nations. Through its member led working groups and

executive leadership, IPIECA brings together the collective expertise of

oil and gas companies and associations. Its unique position within the

industry enables its members to respond effectively to key

environmental and social issues.



www.ipieca.org

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