Safety data sheet



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Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

1/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE 

COMPANY/UNDERTAKING 

1.1 Product identifier 

 

Trade name 

HATRA


 

 

Product code (UVP) 

06268129


 

1.2 Relevant identified uses of the substance or mixture and uses advised against 

 

Use 

Herbicide 



1.3 Details of the supplier of the safety data sheet 

 

Supplier 

 

Bayer CropScience Limited 

230 Cambridge Science Park 

Milton Road 

Cambridge 

Cambridgeshire  CB4 0WB 

United Kingdom 

 

 



Telephone 

+44(0)1223 226500

 

 

Telefax 

+44(0)1223 426240

 

 

Responsible Department 

Email: ukinfo@bayercropscience.com

 

1.4 Emergency telephone no. 

 

Emergency telephone no. 

0800-220876 (UK 24 hr) 



 

 

+44(0)1635-563000 (Overseas 24 hr)

 

 

SECTION 2: HAZARDS IDENTIFICATION 



2.1 Classification of the substance or mixture 

 

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and 

packaging of substances and mixtures, as amended. 

 

Eye irritation: Category 2 

H319 

Causes serious eye irritation.



 

 

Acute aquatic toxicity: Category 1 

H400 

Very toxic to aquatic life.



 

 

Chronic aquatic toxicity: Category 1 

H410 

Very toxic to aquatic life with long lasting effects.



 

 

Classification according to EU Directives 67/548/EEC or 1999/45/EC 

 

Xi Irritant, R36/38 



N Dangerous for the environment, R50/53 

2.2 Label elements 

 

Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and 

packaging of substances and mixtures, as amended. 

 

Hazard label for supply/use required. 



 

Hazardous components which must be listed on the label: 

 


Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

2/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

 Mesosulfuron-methyl 



 Iodosulfuron-methyl-sodium 

 Mefenpyr-diethyl 



 

 

 



 

 

 



 

Signal word

:

  Warning 



 

Hazard statements 

 

H319 


Causes serious eye irritation.

 

H410 



Very toxic to aquatic life with long lasting effects.

 

EUH208 



Contains fatty alcohol ethoxylate alkyl ether. May produce an allergic reaction.

 

EUH401 



To avoid risks to human health and the environment, comply with the instructions for 

use.


 

 

Precautionary statements 

 

P280 


Wear protective gloves/protective clothing/eye protection/face protection. 

P337 + P313  If eye irritation persists: Get medical advice/attention. 

P501 

Dispose of contents/container to a licensed hazardous-waste disposal contractor or 



collection site except for empty clean containers which can be disposed of as non-

hazardous waste. 



2.3 Other hazards 

 

No other hazards known. 

 

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 

3.2 Mixtures 

 

Chemical nature 

 

Oil dispersion (OD) 



Mesosulfuron-methyl/Iodosulfuron-methyl-sodium/Mefenpyr-diethyl 10:2:30 g/l  

 

Hazardous components 

 

R-phrase(s) according to EC directive 67/548/EEC 



Hazard statements according to Regulation (EC) No. 1907/2006 

 

Classification 



Name CAS-No. 



EC-No. 

EC Directive 

67/548/EEC 

Regulation (EC) No 

1272/2008 

Conc. [%] 

Mesosulfuron-

methyl

 

208465-21-8 

606-653-3

 

N; R50/53 



 

Aquatic Acute 1, H400 

Aquatic Chronic 1, H410 

1.04  

Iodosulfuron-

methyl-sodium



 

144550-36-7



 

N; R50/53 



 

Aquatic Acute 1, H400 

Aquatic Chronic 1, H410 

0.20  

Mefenpyr-diethyl

 

135590-91-9 

603-923-2

 

Not classified  



 

Not classified  

3.00  

Docusate sodium



 

577-11-7 

209-406-4

 

Xi; R38, R41 



 

Eye Dam. 1, H318 

Skin Irrit. 2, H315 

>

 



1.00

 – 


<

 

5.00  



Solvent Naphtha 

(petroleum), light 

aromatic

 

64742-95-6 

265-199-0

 

R10 


Xi; R37 

N; R51/53 

Xn; R65 

Flam. Liq. 3, H226 

STOT SE 3, H335 

Asp. Tox. 1, H304 

Aquatic Chronic 2, H411 

>

 



1.00

 – 


<

 

10.00  




Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

3/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

 

Fatty alcohol 

ethoxylate alkyl 

ether


 

1492044-51-

5

 

Xi; R38 


Xi; R41 

R43 


N; R51/53 

 

Eye Dam. 1, H318 

Skin Sens. 1A, H317 

Aquatic Chronic 2, H411 

>

 

10.00 



Solvent Naphtha 

(petroleum), heavy 

aromatic

 

64742-94-5 

265-198-5

 

Xn; R65 


R66 

N; R51/53 



 

Asp. Tox. 1, H304 

Aquatic Chronic 2, H411 

>

 



25.00 

 

Further information 

 

Mesosulfuron-



methyl 

208465-21-8

 

M-Factor: 100 (acute), 100 (chronic) 



Iodosulfuron-

methyl-sodium 

144550-36-7

 

M-Factor: 1,000 (acute) 



 

For the full text of the R-phrases/ Hazard statements mentioned in this Section, see Section 16. 

 

SECTION 4: FIRST AID MEASURES 

4.1 Description of first aid measures 

 

General advice 

Move out of dangerous area. Place and transport victim in stable 

position (lying sideways). Remove contaminated clothing immediately 

and dispose of safely.  

 

Inhalation 

Move to fresh air. Keep patient warm and at rest. Call a physician or 

poison control center immediately.  

 

Skin contact 

Wash off thoroughly with plenty of soap and water, if available with 

polyethyleneglycol 400, subsequently rinse with water.

 

If symptoms 



persist, call a physician.

 

 



 

Eye contact 

Rinse immediately with plenty of water, also under the eyelids, for at 

least 15 minutes.

 

Remove contact lenses, if present, after the first 5 



minutes, then continue rinsing eye.

 

Get medical attention if irritation 



develops and persists.

 

 



 

Ingestion 

Do NOT induce vomiting.

 

Risk of product entering the lungs on 



vomiting after ingestion.

 

Rinse mouth.



 

Call a physician or poison 

control center immediately.

 

To prevent aspiration of swallowed 



product, lay in stable position on one side.

 

 



4.2 Most important symptoms and effects, both acute and delayed 

 

Symptoms 

Headache, Nausea, Dizziness, Somnolence 

 

 

Ingestion may cause gastrointestinal irritation, nausea, vomiting and 

diarrhoea. 

 

 

Aspiration may cause pulmonary oedema and pneumonitis. 

 

 

Inhalation may provoke the following symptoms: 

 

 

Cough, Shortness of breath, Cyanosis, Fever 

 

 

Symptoms and hazards refer to the solvent. 



4.3 Indication of any immediate medical attention and special treatment needed 

 



Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

4/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

Risks 

Contains hydrocarbon solvents. May pose an aspiration pneumonia 

hazard.  

 

Treatment 

Treat symptomatically. In case of ingestion gastric lavage should be 

considered in cases of significant ingestions only within the first 2 

hours. However, the application of activated charcoal and sodium 

sulphate is always advisable. There is no specific antidote.  

 

SECTION 5: FIREFIGHTING MEASURES 

5.1 Extinguishing media 

 

Suitable



 

Water spray, Alcohol-resistant foam, Dry powder, Carbon dioxide 

(CO2) 

 

Unsuitable



 

High volume water jet 

 

5.2 Special hazards arising 

from the substance or 

mixture

 

In the event of fire the following may be released:, Carbon monoxide 

(CO), Nitrogen oxides (NOx), Sulphur oxides, Hydrogen chloride (HCl), 

Hydrogen iodide (HI) 



5.3 Advice for firefighters 

 

Special protective 



equipment for fire-fighters

 

In the event of fire and/or explosion do not breathe fumes. In the event 

of fire, wear self-contained breathing apparatus.  

 

Further information



 

Whenever possible, contain fire-fighting water by diking area with sand 

or earth. Do not allow run-off from fire fighting to enter drains or water 

courses.  

 

SECTION 6: ACCIDENTAL RELEASE MEASURES 

6.1 Personal precautions, protective equipment and emergency procedures 

 

Precautions 

Avoid contact with spilled product or contaminated surfaces. Use 

personal protective equipment. 

 

 

6.2 Environmental 

precautions

 

Do not allow to get into surface water, drains and ground water. If 

spillage enters drains leading to sewage works inform local water 

company immediately. If spillage enters rivers or watercourses, inform 

the Environment Agency (emergency telephone number 0800 

807060). 



 

6.3 Methods and materials for containment and cleaning up 

 

Methods for cleaning up

 

Soak up with inert absorbent material (e.g. sand, silica gel, acid 

binder, universal binder, sawdust). Clean contaminated floors and 

objects thoroughly, observing environmental regulations. Keep in 

suitable, closed containers for disposal. 

 

 

6.4 Reference to other 

sections

 

Information regarding safe handling, see section 7. 

Information regarding personal protective equipment, see section 8. 

Information regarding waste disposal, see section 13. 

 

SECTION 7: HANDLING AND STORAGE 

7.1 Precautions for safe handling 

 



Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

5/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

Advice on safe handling

 

No specific precautions required when handling unopened 

packs/containers; follow relevant manual handling advice. Ensure 

adequate ventilation. 



 

 

Advice on protection 



against fire and explosion

 

Keep away from heat and sources of ignition. 



 

 

Hygiene measures



 

Avoid contact with skin, eyes and clothing. Keep working clothes 

separately. Wash hands before breaks and immediately after handling 

the product. Remove soiled clothing immediately and clean thoroughly 

before using again. Garments that cannot be cleaned must be 

destroyed (burnt). 



 

7.2 Conditions for safe storage, including any incompatibilities  

 

Requirements for storage 



areas and containers

 

Keep containers tightly closed in a dry, cool and well-ventilated place. 

Store in original container. Store in a place accessible by authorized 

persons only. Store bulk material and packed materials in a closed 

warehouse or under cover protected against direct sunlight and frost. 

Protect from freezing. 



 

 

Advice on common storage



 

Keep away from food, drink and animal feedingstuffs. 



 

 

Suitable materials



 

Coex EVOH (1000L IBC) 



 

 

7.3 Specific end uses



 

Refer to the label and/or leaflet.



 

 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 



8.1 Control parameters 

 

Components CAS-No. 



Control 

parameters 

Update 

Basis 

Iodosulfuron-methyl-sodium 144550-36-7 

mg/m3 


(TWA) 

 

 



OES BCS* 

 

 



*OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" 

 

Additional advice 

 

Observe: Exposure Limits In Air, Group 3: 100 mg/m³/ 20 ppm. (aromatic-rich hydrocarbon mixes with > 



25% aromatics TRGS 901, No. 72). 

8.2 Exposure controls 

 

Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment) 



Regulations 2004). Engineering controls should be used in preference to personal protective 

equipment wherever practicable. Refer also to COSHH Essentials. 

 

Personal protective equipment 

In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the 

following recommendations would apply. 



 

 

Respiratory protection 

Respiratory protection is not required under anticipated 

circumstances of exposure. 

Respiratory protection should only be used to control residual risk of 

short duration activities, when all reasonably practicable steps have 

been taken to reduce exposure at source e.g. containment and/or 

local extract ventilation. Always follow respirator manufacturer's 

instructions regarding wearing and maintenance. 

 

 



Hand protection 

Wear CE Marked (or equivalent) nitrile rubber gloves (minimum 




Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

6/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

thickness of 0,4 mm). Wash when contaminated and dispose of 

when contaminated inside, when perforated or when contamination 

on the outside cannot be removed. Wash hands frequently and 

always before eating, drinking, smoking or using the toilet. 

 

Eye protection 

Wear goggles (conforming to EN166, Field of Use = 5 or equivalent). 

 

Skin and body protection 

Wear standard coveralls and Category 3 Type 6 suit. 

If there is a risk of significant exposure, consider a higher protective 

type suit. 

Wear two layers of clothing wherever possible. Polyester/cotton or 

cotton overalls should be worn under chemical protection suit and 

should be professionally laundered frequently. 

If chemical protection suit is splashed, sprayed or significantly 

contaminated, decontaminate as far as possible, then carefully 

remove and dispose of as advised by manufacturer. 

 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 



9.1 Information on basic physical and chemical properties 

 

Form 

Liquid

 

 



Colour 

beige 


 

 

Odour 

aromatic

 

 



pH

 

7.0 - 8.5 at 10 % (23 °C) (deionized water)

 

 

 



Flash point 

ca.93 °C 

 

 

Autoignition temperature 



 

405 °C at 

 

1,021 hPa



 

 

Density 

ca.

 

1.00 g/cm³ at



 

20 °C


 

 

 



Water solubility 

dispersible

 

 

Partition coefficient: n-



octanol/water 

Mesosulfuron-methyl: log Pow: -0.48

 

 

Iodosulfuron-methyl-sodium: log Pow: -0.7

 

 

Mefenpyr-diethyl: log Pow: 3.83 at 21 °C

 

 

Viscosity, dynamic 



30 - 150 mPa.s at 

 

20 °C Velocity gradient 20 /s



 

 

 

25 - 100 mPa.s at 

 

20 °C Velocity gradient 100 /s



 

 

Surface tension 

29.9 mN/m at

 

 40 °C  



Determined in the undiluted form.

 

 



Oxidizing properties 

No oxidizing properties

 

 

Explosivity 



Not explosive 

 

 



9.2 Other information 

Further safety related physical-chemical data are not known. 

 

SECTION 10: STABILITY AND REACTIVITY 

10.1 Reactivity 

 

Thermal decomposition



 

Stable under normal conditions. 

 

10.2 Chemical stability

 

Stable under recommended storage conditions. 



 


Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

7/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

 

10.3 Possibility of 



hazardous reactions

 

No hazardous reactions when stored and handled according to 

prescribed instructions.  

 

 



10.4 Conditions to avoid 

Extremes of temperature and direct sunlight. 

 

 

10.5 Incompatible materials



 

Store only in the original container.



 

 

 



10.6 Hazardous 

decomposition products

 

No decomposition products expected under normal conditions of use. 

 

SECTION 11: TOXICOLOGICAL INFORMATION

 

11.1 Information on toxicological effects 

 

Acute oral toxicity 

LD50 (rat)  >= 5,000 mg/kg 

 

Acute inhalation toxicity 

 

During intended and foreseen applications, no respirable aerosol is 



formed. 

 

Acute dermal toxicity 

LD50 (rat)  > 4,000 mg/kg 

 

Skin irritation 

Moderate skin irritation. (rabbit) 

 

Eye irritation 

Irritating to eyes. (rabbit) 

 

Sensitisation 

Non-sensitizing. (guinea pig) 

OECD Test Guideline 406, Buehler test 

 

Assessment repeated dose toxicity 

 

Mesosulfuron-methyl did not cause specific target organ toxicity in experimental animal studies.  



Iodosulfuron-methyl-sodium did not cause specific target organ toxicity in experimental animal studies.  

Mefenpyr-diethyl did not cause specific target organ toxicity in experimental animal studies.  

 

Assessment Mutagenicity 

 

Mesosulfuron-methyl was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.  



Iodosulfuron-methyl-sodium was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.  

Mefenpyr-diethyl was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.  

 

Assessment Carcinogenicity 

 

Mesosulfuron-methyl was not carcinogenic in lifetime feeding studies in rats and mice.  



Iodosulfuron-methyl-sodium was not carcinogenic in lifetime feeding studies in rats and mice.  

Mefenpyr-diethyl was not carcinogenic in lifetime feeding studies in rats and mice.  

 

Assessment toxicity to reproduction 

 

Mesosulfuron-methyl did not cause reproductive toxicity in a two-generation study in rats.   



Iodosulfuron-methyl-sodium did not cause reproductive toxicity in a two-generation study in rats.   

Mefenpyr-diethyl did not cause reproductive toxicity in a two-generation study in rats.   

 

Assessment developmental toxicity 

 

Mesosulfuron-methyl did not cause developmental toxicity in rats and rabbits.   



Iodosulfuron-methyl-sodium did not cause developmental toxicity in rats and rabbits.   

Mefenpyr-diethyl caused developmental toxicity only at dose levels toxic to the dams. The 

developmental effects seen with Mefenpyr-diethyl are related to maternal toxicity.   



Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

8/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

 

SECTION 12: ECOLOGICAL INFORMATION 



12.1 Toxicity 

 

Toxicity to fish 

LC50 (Rainbow trout (Oncorhynchus mykiss))  8.83 mg/l  

Exposure time: 96 h 

 

Toxicity to aquatic 

invertebrates 

EC50 (Water flea (Daphnia magna))  7.6 mg/l  

Exposure time: 48 h 

 

 



Toxicity to aquatic plants 

EC50 (Pseudokirchneriella subcapitata)  6.71 mg/l  

Exposure time: 72 h 

 

 

EC50 (Lemna gibba (duckweed))  88.4 µg/l  

Exposure time: 7 d 



12.2 Persistence and degradability 

 

Biodegradability 

Mesosulfuron-methyl:  

not rapidly biodegradable  



 

Iodosulfuron-methyl-sodium:  

not rapidly biodegradable  

 

Mefenpyr-diethyl:  

not rapidly biodegradable  

 

Koc 

Mesosulfuron-methyl: Koc: 92 

 

Iodosulfuron-methyl-sodium: Koc: 45 



 

Mefenpyr-diethyl: Koc: 625 



12.3 Bioaccumulative potential 

 

Bioaccumulation 

Mesosulfuron-methyl:  

Does not bioaccumulate. 



 

Iodosulfuron-methyl-sodium:  

Does not bioaccumulate. 

 

Mefenpyr-diethyl: Bioconcentration factor (BCF) 232 

Does not bioaccumulate. 

12.4 Mobility in soil 

 

Mobility in soil 

Mesosulfuron-methyl: Moderately mobile in soils 

 

Iodosulfuron-methyl-sodium: Mobile in soils 



 

Mefenpyr-diethyl: Slightly mobile in soils 



12.5 Results of PBT and vPvB assessment 

 

PBT and vPvB assessment 

Mesosulfuron-methyl: This substance is not considered to be persistent, 

bioaccumulative and toxic (PBT). This substance is not considered to be 

very persistent and very bioaccumulative (vPvB).  

 

Iodosulfuron-methyl-sodium: This substance is not considered to be 

persistent, bioaccumulative and toxic (PBT). This substance is not 

considered to be very persistent and very bioaccumulative (vPvB).  



 

Mefenpyr-diethyl: This substance is not considered to be persistent, 

bioaccumulative and toxic (PBT). This substance is not considered to be 

very persistent and very bioaccumulative (vPvB).  



12.6 Other adverse effects 

 

Additional ecological 



information 

No other effects to be mentioned. 




Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

9/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

 

SECTION 13: DISPOSAL CONSIDERATIONS 



13.1 Waste treatment methods 

 

Product



 

In accordance with current regulations and, if necessary, after 

consultation with the site operator and/or with the responsible authority, 

the product may be taken to a waste disposal site or incineration plant. 



 

Advice may be obtained from the local waste regulation authority (part 

of the Environment Agency in the UK). 

 

Contaminated packaging



 

Small containers (< 10 l or < 10 kg) should be rinsed thoroughly using 

an integrated pressure rinsing device, or, by manually rinsing three 

times. 


 

Add washings to sprayer at time of filling. 



 

Dispose of empty and cleaned packaging safely. 



 

Large containers (> 25 l or > 25 kg) should not be rinsed or re-used for 

any other purpose. 

 

Return large containers to supplier. 



 

Follow advice on product label and/or leaflet. 

 

Waste key for the unused 

product

 

020108 agrochemical waste containing dangerous substances 

 

SECTION 14: TRANSPORT INFORMATION 



 

ADR/RID/ADN 

14.1 UN number 



3082  

14.2 Proper shipping name 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, 

N.O.S. 


 (IODOSULFURON-METHYL 

SODIUM, MESOSULFURON-

METHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY 

AROMATIC MIXTURE)



 

14.3 Transport hazard class(es) 

14.4 Packing group 



III

 

14.5 Environm. Hazardous Mark 



YES 

Hazard no. 

90

 

Tunnel Code 



E

 

 



This classification is in principle not valid for carriage by tank vessel on inland waterways. Please 

refer to the manufacturer for further information. 

 

IMDG 

14.1 UN number 



3082  

14.2 Proper shipping name 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, 

N.O.S. 


 

(IODOSULFURON-METHYL SODIUM, MESOSULFURON-

METHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY 

AROMATIC MIXTURE)

 

14.3 Transport hazard class(es) 



9

 

14.4 Packing group 



III

 

14.5 Marine pollutant 



YES

 

 



IATA 

14.1 UN number 



3082  


Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

10/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

14.2 Proper shipping name 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, 

N.O.S. 


 

(IODOSULFURON-METHYL SODIUM, MESOSULFURON-

METHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY 

AROMATIC MIXTURE )

 

14.3 Transport hazard class(es) 



9

 

14.4 Packing group 

III

 

14.5 Environm. Hazardous Mark 



YES

 

 



UK 'Carriage' Regulations 

 

14.1 UN number 



3082  

14.2 Proper shipping name 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, 

N.O.S. 


 

(IODOSULFURON-METHYL SODIUM, MESOSULFURON-

METHYL, SOLVENT NAPHTHA (PETROLEUM) HEAVY 

AROMATIC MIXTURE)

 

14.3 Transport hazard class(es) 



14.4 Packing group 

III

 

14.5 Environm. Hazardous Mark 



YES

 

Emergency action code



 

3Z 


 

14.6 Special precautions for user 

See sections 6 to 8 of this Safety Data Sheet. 

 

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 

No transport in bulk according to the IBC Code. 

 

SECTION 15: REGULATORY INFORMATION 

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 

 

UK and Northern Ireland Regulatory References

 

 

This material may be subject to some or all of the following regulations (and any subsequent 



amendments). Users must ensure that any uses and restrictions as indicated on the label and/or leaflet 

are followed.

 

 

Transport



 

 

Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 



2009 No 1348)  

Merchant Shipping (Dangerous Goods and Marine Pollutants) Regulations 1997 (SI 1997 No 2367)  

Air Navigation Dangerous Goods Regulations 2002 (SI 2002 No 2786)

 

 



Supply and Use

 

 

Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No 716)  



Chemical (Hazard Information and Packaging for Supply) (Northern Ireland) Regulations 2009   

Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No 2677)  

EH40 Occupational Exposure Limits - Table 1 List of approved workplace exposure limits  

Control of Pesticide Regulations 1986  

Dangerous Substances and Explosive Atmospheres Regulations 2002

 

 



Waste Treatment

 

 

Environmental Protection Act 1990, Part II  



Environmental Protection (Duty of Care) Regulations 1991  

The Waste Management Licensing Regulations 1994 (as amended)  

Hazardous Waste Regulations 2005 (Replacing Special Waste Regulations 1996 as amended)  



Bayer CropScience 

 

SAFETY DATA SHEET



 

according to Regulation (EC) No. 1907/2006

 

 

 

HATRA

 

11/11

 

Version  5



 / 

GB 


Revision Date: 11.07.2014

 

102000008429



 

Print Date: 11.07.2014

 

 

 



 

Landfill Directive  

Regulation on Substances That Deplete the Ozone Layer 1994 (EEC/3093/94)  

Water Resources Act 1991  

Anti-Pollution Works Regulations 1999 

 

Further information



 

 

WHO-classification: III (Slightly hazardous) 



15.2 Chemical Safety Assessment 

 

A chemical safety assessment is not required. 



 

SECTION 16: OTHER INFORMATION 

Text of R-phrases mentioned in Section 3

 

 

R10



 

Flammable.

 

R37


 

Irritating to respiratory system.

 

R38


 

Irritating to skin.

 

R41 


R43

 

Risk of serious damage to eyes. 



May cause sensitisation by skin contact.

 

R50/53



 

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 

environment.

 

R51/53



 

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 

environment.

 

R65



 

Harmful: may cause lung damage if swallowed.

 

R66


 

Repeated exposure may cause skin dryness or cracking.

 

 

Text of the hazard statements mentioned in Section 3



 

 

H226



 

Flammable liquid and vapour.

 

H304


 

May be fatal if swallowed and enters airways.

 

H315


 

Causes skin irritation.

 

H317


 

May cause an allergic skin reaction.

 

H318


 

Causes serious eye damage.

 

H335


 

May cause respiratory irritation.

 

H400


 

Very toxic to aquatic life.

 

H410


 

Very toxic to aquatic life with long lasting effects.

 

H411


 

Toxic to aquatic life with long lasting effects.

 

 

The above information is intended to give general health and safety guidance on the storage and 



transport of the product.

 

It is not intended to apply to the use of the product for which purposes the product label and any 



appropriate technical usage literature available should be consulted and any relevant licenses, 

consents or approvals complied with.

 

The requirements or recommendations of any relevant site or working procedure, system or policy in 



force or arising from any risk assessment involving the substance or product should take precedence 

over any of the guidance contained in this safety data sheet where there is a difference in the 

information given.

 

The information provided in this safety data sheet is accurate at the date of publication and will be 



updated as and when appropriate.

 

No liability will be accepted for any injury, loss or damage resulting from any failure to take account of 



information or advice contained in this safety data sheet.

 

 



Changes since the last version are highlighted in the margin. This version replaces all previous 

versions. 



 



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