Concise International Chemical Assessment Document 33
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- Bu səhifədəki naviqasiya:
- Occupational exposure limits
- SEE IMPORTANT INFORMATION ON THE BACK. IPCS
- TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING
- EXPOSURE PREVENT DISPERSION OF DUST! STRICT HYGIENE! Inhalation
- SPILLAGE DISPOSAL PACKAGING LABELLING
- EMERGENCY RESPONSE STORAGE
- Effects of short-term exposure
- PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 1640°C Melting point: 725°C Density: 3.6 g/cm 3 Solubility in water: reaction LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information ©IPCS 2000 1052 BARIUM IMPORTANT DATA Physical State; Appearance YELLOWISH TO WHITE LUSTROUS SOLID IN VARIOUS FORMS.
Dust explosion possible if in powder or granular form, mixed with air.
The substance may spontaneously ignite on contact with air (if in powder form). The substance is a strong reducing agent and reacts violently with oxidants and acids. Reacts violently with halogenated solvents. Reacts with water, forming flammable/explosive gas (hydrogen - see ICSC 0001), causing fire and explosion hazard.
TLV: 0.5 mg/m 3 (as TWA) (ACGIH 1999). Routes of exposure The substance can be absorbed into the body by ingestion. Effects of short-term exposure The substance irritates the eyes, the skin and the respiratory tract.
Reacts violently with fire extinguishing agents such as water, bicarbonate, powder, foam, and carbon dioxide. Rinse contaminated clothes (fire hazard) with plenty of water.
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission © IPCS 2000
International Programme on Chemical Safety BARIUM CHLORATE 0613 October 2000 CAS No: 13477-00-4 RTECS No: FN9770000 UN No: 1445 EC No: 017-003-00-8 Chloric acid, barium salt BaCl
2 O 6 / Ba(ClO 3 ) 2 Molecular mass: 304.2 EXPOSURE__ACUTE_HAZARDS/SYMPTOMS__PREVENTION__FIRST_AID/FIRE_FIGHTING'>TYPES OF HAZARD/ EXPOSURE ACUTE HAZARDS/SYMPTOMS PREVENTION FIRST AID/FIRE FIGHTING FIRE Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. NO contact with flammable substances. NO contact with organic substances, metal powders, ammonium salts, and reducing agents.
In case of fire in the surroundings: all extinguishing agents allowed. EXPLOSION Risk of fire and explosion on contact with : see Chemical Dangers.
Do NOT expose to friction or shock. Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
Cough. Sore throat. (See Ingestion). Ventilation (not if powder), local exhaust, or breathing protection. Fresh air, rest. Artificial respiration if indicated. Refer for medical attention. Skin Redness.
Protective gloves. First rinse with plenty of water, then remove contaminated clothes and rinse again. Refer for medical attention.
Redness. Pain. Safety goggles, or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Abdominal pain. Blue lips or fingernails. Blue skin. Confusion. Convulsions. Diarrhoea. Dizziness. Headache. Nausea. Unconsciousness. Vomiting. Weakness. Do not eat, drink, or smoke during work. Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention.
Consult an expert if large spill! Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water. Do NOT absorb in saw-dust or other combustible absorbents. Do NOT let this chemical enter the environment. (Extra personal protection: P2 filter respirator for harmful particles). O Symbol Xn Symbol R: 9-20/22 S: (2-)13-27 UN Hazard Class: 5.1 UN Subsidiary Risks: 6.1 UN Pack Group: II Do not transport with food and feedstuffs.
Transport Emergency Card: TEC (R)-812 NFPA Code: H2; F0; R1; ox Separated from combustible and reducing substances, ammonium-containing substances, metal powders, food and feedstuffs.
Decomposes below melting point: 250°C Density: 3.2 g/cm 3 Solubility in water, g/100 ml: 27.4 (good) LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information ©IPCS 2000 0613 BARIUM CHLORATE IMPORTANT DATA Physical State; Appearance COLOURLESS CRYSTALLINE POWDER Chemical dangers Shock-sensitive compounds are formed with organic compounds, reducing agents, ammonia-containing agents, and metal powders. The substance decomposes violently on heating producing oxygen and toxic fumes, causing fire and explosion hazard. The substance is a strong oxidant and reacts with combustible and reducing materials.
TLV (as Ba): 0.5 mg/m 3 (as TWA) A4 (ACGIH 1999). 0.5 mg/m 3 EC OELs
Routes of exposure The substance can be absorbed into the body by inhalation and by ingestion.
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered. Effects of short-term exposure The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the blood and nervous system, resulting in formation of methaemoglobin. Exposure could cause hypokalemia, resulting in cardiac disorders and muscular disorders. The effects may be delayed. Medical observation is indicated. Exposure may result in death.
The substance is harmful to aquatic organisms. NOTES Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of paralysis do not become manifest until some hours have passed. Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available. Rinse contaminated clothes (fire hazard) with plenty of water. 10294-38-9 is a CAS registry number for Barium chlorate, monohydrate. Will turn shock-sensitive if contaminated with: see Chemical Dangers.
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