Environmental Impact of Abandoned Mine Waste: a review



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Summary and Conclusions


Existing literature shows that there are not significant differences among the various mine sites investigated, irrespective of the nature of ore deposits. The abandoned mine waste contain significant amounts of polluting elements potentially dangerous to the environment. The main differences concern the waste morphology (dumps, tailings, roastings, soil), the particle-size, the hydrological regime, the pH conditions, which determine the fate of metals in the environment.

In particular, literature summarised in this review indicates that:
Sulphides that occur in flotation basins show comparatively low degrees of alteration in comparison to exposed mine dumps: scarce effective porosity, shallow water table and superficial capillary fringe have hindered sulphide weathering; near neutral pH and secondary mineralogical phases indicate that until now reactions producing and consuming acidity balance each other;

Inversely, the hydraulic unsaturated conditions and the fine size of flotation tailings have enhanced the weathering of sulphides;

The roasting dumps are characterised by high contents of metals and low pH values. However, they appear to be a less significant threat to the environment, at least in the short term, because the metalliferous phases are partially enclosed within relatively coarse quartz grains, and adsorbed onto alumosilicates, thus slowing the weathering processes;

Stream water shows acid to neutral pH values, and maintain high metal contents as far as 1 km downstream of mine wastes; more distal waters are neutral as a consequence of dilution with unpolluted water and buffering reactions with carbonate bedrock;

The transport of polluted stream sediments causes contamination as far as 5 km downstream of the mine wastes.

Aeolian transport and suspended particulate matter in streams seem to significantly contribute in disseminating metal pollution over large areas, even at distance from the metal source.


The results presented shed light on the environmental effects of mine wastes, give a thorough understanding of the polluting potential of mine waste, and can be an useful basis for planning possible remediation projects. Yet, the variation of the above cited conditions could cause the establishment of more acidic and leaching conditions and, therefore, an increase in metal mobilization, and major environmental hazard.

Based on available data, a possible remediation plan could include the preservation of the existing conditions, enlarging the impoundment surface by building of settling ponds for drainage waters storage. Afterwards, the polluted sediments could be stored into the flotation basins, and mixed with buffering compounds such as limestone for neutralisation, and prevent acidic drainage waters production. Finally, revegetation of the whole mined area with metal-tolerant plants could take place, and the contaminated land be restored.




References


Abrahams, P. W. (2002) - Soils: their implications to human health. Sci Tot. Envir., 291, 1-32.

Adriano, D.C. (2001) - Trace Elements in Terrestrial Environments – Biogeochemestry, Bioavailability and Risk of Metals. Springer Verlag, N.Y.

Agricola, G. (1556) – De re metallica. Translated by Hoover, H.C., 1950. Dover Publishers, N.Y., 638 pp.

Aleksander-Kwaterczak, U. and Helios-Rybicka, E. (2009) – Contaminated sediments as a potential source of Zn, Pb and Cd for a river system in the historical metalliferous ore mining and smelting industry area of South Poland. Journal of Soils and Sediments, 9, 13-22.

Alloway, B.J. (1995). Soil processes and the behavior of metals. In: Alloway B.J. (Ed.) Heavy metals in soils, 2nd ed.: 11-37. Blackie Academic and Professional, London.

Angelone, M. and Bini, C. (1992) - Trace elements concentrations in soils and plants of Western Europe. in Adriano D.C. (Ed.) Biogeochemistry of Trace Metals: 19-60. Lewis Publishers.

Baker, A. J. M. (1981) – Accumulators And Excluders Strategies In The Response of Plants to Heavy Metals: J. of Plant Nutrition, 3, 643-654.

Baker, A. M. J. and Brooks, R.R. (1989) – Terrestrial Higher Plants Which Hyperaccumulate Metallic Elements – A Review Of Their Distribution, Ecology And Phytochemistry. Biorecovery, 1, 81-126.

Baldini, E., Benvenuti, M., Corsini, F., Costagliola, P., Mascaro, I., Tanelli, G., Benesperi, R., Gabbrielli, R., Gonnelli, C. (2001) – Study of soil-plant interactions in the Temperino Cu-Zn-Pb mine (Campiglia Marittima, Southern Tuscany, Italy. Proc. VI ICOBTE Conf., Guelf (ON), 574.

Bargagli, R. (1995) – Effects of abandoned mercury mines on terrestrial and aquatic ecosystems. In: R. Prost, (edit.) Contaminated soils. INRA, Paris, 255-265.

Bech, J., Rustullet, J., Garrigo, J., Tobias, F.& Martinez, R. (1997). The iron content of some red mediterranean soils from NE Spain and its pedogenic significance. Catena, 28, 211-229.

Benvenuti, M., Mascaro, I., Corsini, F., Ferrari M., Lattanzi, P., Parrini P. Costagliola P., Tanelli, G. (2000) – Environmental mineralogy and geochemistry of waste dumps at the Pb(Zn)-Ag Bottino mine, Apuane Alps, Italy. Eur. J. Mineral., 12, 441-453.

Benvenuti, M., Mascaro, I., Corsini, F., Costagliola P., Parrini P.,Lattanzi, P., Tanelli G. (1999) – Environmental problems related to sulfide mining in Tuscany. Chronique de la recherche miniere, 534, 29-45.

Benvenuti, M., Mascaro, I., Corsini, F., Lattanzi, P., Tanelli, G. (1997) – Mine waste dumps and heavy metal pollution in abandoned mining district of Boccheggiano (southern Tuscany, Italy). Environ. Geol., 30, 238-243.

Berger, A.C., Bethke, C.M., Krumhans, J.L. (2000) – A process model of natural attenuation in drainage from a historic mining district. Appl. Geochem., 15, 655-666.

Bernard, A.M. (1995) – Effects of heavy metals in the environment on the human health. In: R. Prost, (edit.) Contaminated soils. INRA, Paris, 21-34.

Bertolani, M. (1958) – Osservazioni sulle mineralizzazioni metallifere del Campigliese (Livorno). Per. Miner., 27, 311-344.

Bettiol, C., Minello, F., Gobbo, L., Sartorato, E., Argese, E. (2010) – Bioaccumulation of As and heavy metals by Pteris vittata from soil contaminated by glass industry wastes: a small-scale field study. Proc. VII Int. Conf. Phytotechnologies, September, 26-29, Parma, Italy, p.26.

Bini, C. (2010) – From soil contamination to land restoration. In: Contaminated soils: Environmental Impact, Disposal and Treatment (R.V. Steinberg edit.), Nova Science Publisher, New York (ISBN 978-1-60741-791-0).

Bini, C. (2009) – Soil restoration: remediation and valorization of contaminated soils. In: E.A.C. Costantini (ed.): Manual of methods for soil and land evaluation. Science Publisher, Enfield (NH), pp137-160.

Bini, C. and Gaballo, S. (2006) – Pedogenic trends in Anthrosols developed in sulfidic mine spoils: a case study in the Temperino mine archaeological area (Campiglia Marittima, Tuscany, Italy). Quaternary International, 156 /157, 70-78.

Bini, C. and Zilioli, D. (2010) - Soils as a target of anthropogenic landscape changes in alpine areas (Dolomites, Northern Italy). Proc. 19° World Congress of Soil Science, Brisbane, 103-105 (in DVD).

Bini, C., Gaballo, S., Zilocchi, L. (2004) – Land contamination and soil-plant interactions in the Temperino Cu-Zn-Pb mine (Campiglia M.ma, Southern Tuscany, Italy). Proc. 1th Eur. Geosci. Un. Congr., Nice, 6, A-07153.

Bini, C., Fontana, S., Whasha, M. (2010) - Land contamination by mine dumps, plant toxicity and restoration perspectives by phytoremediation. Proc. IV Int. Conf. Air, Water and Soil Quality, Imola, June, 24-25, pp

Bini, C., Maleci, L., Gabbrielli, R., Paolillo, A. (2000) – Biological perspectives in soil remediation with reference to chromium. In: D.L. Wise, D.J. Trantolo (eds): Bioremediation of contaminated soils. Marcel Decker, Inc., NY, 663-675.

Bini, C., Fontana, S., Gallo, M., Whasha, M., Zilioli, D. (2011) - Background levels of PTEs in terraced agroecosystems of NE Italy: geogenic vs anthropogenic enrichment and phytoremediation perspectives. Geophysical Research Abstracts, Vol. 13, EGU2011-12233.

Bini, C., Angelone, M., De Siena, C., Vaselli, O., Gentili, L. (1995) - Livelli di elementi maggiori ed in traccia nelle piante e nei suoli del Monte Capanne (isola d’Elba). Proc. 16th Congress SITE, pp. 503-505.

Bini, C., Dal Maso, C., Angelone, M., Spaziani, F., Morgavi, D., Tateo, F. (2006) - Nuovi e vecchi dubbi sulle terre rosse. In: Suolo, Ambiente, Paesaggio. Atti Conv. Naz. SISS (a cura di C. Gessa, S. Lorito, G. Vinello, L. Vittori Antisari), 9-19. Tipolitografia F.G., Modena.

Bockheim, J.G. (1980) – Solutions and use of chronofunctions in studying soil development. Geoderma, 24, 71-82.

Bockheim, J.G. (1990) – Soil development rate in the Transarctic mountains. Geoderma, 47, 59-70.

Bradshaw, A.D. and Chadwick, M.J. (1980) – The restoration of land. Blackwell Scientific Publications, Oxford, England.

Burtet-Fabris, B., Omenetto, P. (1971) – Osservazioni sul giacimento filoniano a solfuri di Zn, Pb, Cu di Fenice Capanne presso Massa Marittima, Toscana. Rend. SIMP, 27, 393-435.

Burykin, A.M. (1985) – The rate of pedogenesis in technogenic landscapes in connection with their reclamation. Soviet Soil Science, 2, 81-93.

Caboi, R., Cidu, R., Fanfani, L., Lattanzi, P., Zuddas, P. (1999) – Environmental mineralogy and geochemistry of the abandoned Pb-Zn Montevecchio-Ingurtosu mining district, Sardinia, Italy. Chronique de la Recherche Miniere, 534, 29-45.

Cappuyns, V., Swennen, R., Vandamme, A., Niclaes, M. (2006) – Environmental impact of the former Pb-Zn mining and smelting in East Belgium. Journal of Geochemical Exploration, 88, 6-9.

Casini, A. (1993) - Archeologia di un territorio minerario: i Monti di Campiglia. Quad. Mus. Stor. Nat. Livorno, 13, suppl. 2, 303-314.

Casiot, C., Egal, M., Elbaz-Poulichet, F., Bruneel, O., Bancon-Montigny, C., Cordier, M.A., Gomez, E., Aliaume, C. (2009) – Hydrological and geochemical control of metals and arsenic in a Mediterranean river contaminated by acid mine drainage (the Amous River, France); preliminary assessment of impacts on fish (Leiciscus cephalus). Appl. Geochem., 24, 787-799.

Chaney, R., Brown, S., Li, Y., Angle, S., Homer, F., Green, C. (1995) – Potential use of metal hyperaccumulators. Mining Environ. Man., 3, 9-11.

Cidu, R. and Fanfani, L. (2002) – Overview of the environmental geochemistry of mining district in southwestern Sardinia, Italy. Geochemistry: Exploration, Environment, Analysis, 2, 243-251.

Cidu, R., Biddau, R., Fanfani, L. (2009) – Impact of past mining activity on the quality of groundwater in SW Sardinia (Italy). J. Geochem. Explor., 100, 125-132.

Cipriani, C., Tanelli, G. (1983) – Risorse minerarie ed industria estrattiva in Toscana – Note storiche ed economiche. Mem. Acc. Tosc. Sci. Lett. La Colombaria, 48, 243-283.

Conesa, H.M., Robinson, B.H., Schulin, R., Nowack, B. (2008) – Metal extractability in acidic and neutral mine tailings from the Cartagena-La Union mining district (SE Spain). Appl. Geochem., 23, 1232-1240.

Corretti, A., Benvenuti, M. (2001) – The beginning of iron metallurgy in Tuscany with special reference to Etruria Mineraria. Mediterr. Archaeol., 14, 127-145.

Corsini, F., Cortecci, G., Leone, G.& Tanelli, G. (1980) - Sulfur isotope study of the skarn-(Cu-Pb-Zn) sulphide deposit of Valle del Temperino, Campiglia Marittima, Tuscany, Italy. Econ. Geol., 75, 83-96.

Corsini, F., Lattanzi, P., Tanelli, G. (1 975) – Contenuto in Fe delle blende del giacimento a solfuri di Cu, Pb, Zn di Fenice Capanne (Toscana): condizioni ambientali di formazione. Rend. Soc. It. Miner. Petr., 31, 351-354.

Costagliola, P., Benvenuti, M., Chiarantini, L., Bianchi, S., Di Benedetto, F., Paolieri, M., Rossato, L. (2008) – Impact of ancient metal smelting on arsenic pollution in the Pecora River Valley, Southern Tuscany, Italy. Applied Geochem., 23, 1241-1259.

D’Achiardi, G. (1927) – L’industria mineraria e metallurgica in Toscana al tempo degli Etruschi. Studi Etruschi, I, 411-420.

Dall’Aglio, M., Da Roit, R., Orlandi, C., Tonani, F. (1966) – Prospezione geochimica del mercurio. Distribuzione del mercurio nelle alluvioni della Toscana. L’industria Mineraria, XVII, 391-398.

Da Pelo, S., Musu, E., Cidu, R., Frau, F. & Lattanzi, P. (2009) – Release of toxic elements from rocks and mine wastes at the Furtei gold mine (Sardinia, Italy). J. Geochem. Explor., 100, 142-152.

Davies, B.E. (1980) – Base metal mining and heavy metal contamination of agricultural land in England and Wales. In: Inorganic pollution and agriculture. Ministry of the Agriculture, Fisheries and Food, Reference Book n° 326, paper 12, London, pp142-156.

Davies, B.E. (1987) – Consequences of environmental contamination by lead mining in Wales. Hydrobiologia, 149, 213-220.

Davies, B.E. and White, H.M. (1981) – Environmental pollution by wind blown lead mine waste: a case study in Wales, U.K.. Sci. Total Environ., 20, 57-74.

Davies, B.E. and Roberts, L.J. (1975) – Heavy metals in soils and radish in a mineralized limestone area of Wales, Great Britain. Sci Tot. Environ., 4: 249-261.

Davies, B.E., Jones, K.C. and Peterson, P.J. (1983) – Metalliferous mine spoils in Wales : a toxic and hazardous waste. Proc. 4th Int. Conf., Heavy Metals in the Environment, Heidelberg, 984-987.

Delgado, J., Sarmiento, A.M., Condesso De Melo, M.T., Nieto, J.M. (2009) - Environmental Impact of Mining Activities in the Southern Sector of the Guadiana Basin (SW of the Iberian Peninsula). Water, Air, & Soil Pollution 199, 323-341

Deschamps, Y., Dagallier, G., Macaudiere, J., Marignac, C., Moine, B., Saupé, F. (1983) – le gisement de pyrite.hematite de Valle Giove (Rio Marina, Ile d’Elbe, Italie). Schweizerische Mineralogische und Petrographische Mitteilungen, 63, 149-165.

Dill, H.D. (2009) – Pyrometallurgical relicts of Pb-Cu-Fe deposits in south-eastern Germany: an exploration tool and a record of mining history. J. Geochem. Explor., 100, 37-50.

Dinelli, E., Lombini, A. (1996) - Metal distribution in plants growing on copper mine spoils in Northern Appenines, Italy: the evaluation of seasonal variations. Applied Geochemistry, 11, 375-385.

E.C. (2006) – Directive 2006/21/EC of the European Parliament and of the Council of 15 march 2006 on the management of waste from extractive industries and amending Directive 2004/35/EC. The Council and Commission Official Journal, 102, 15-34, 11/04/2006.

Ernst, W.H.O. (1996) – Bioavailability of heavy metals and decontamination of soils by plants. Appl. Geochem., 11, (1-2), 163-168.

Fanfani, L. (1997) – Alterazione dei solfuri e problemi ambientali. Plinius, 17, 99-103.

Fanfani, L., Zuddas, P., Chessa, A. (1997) – Heavy metals speciation analysis as a tool for studying mine tailings weathering. J. Geochem. Explor., 58, 241-248.

Ferguson, K.D. and Erickson, P.M. (1988) - Pre-mine prediction of acid mine drainage. In: W. Salomons and U. Förstner, Editors, Environmental Management of Solid Waste: Dredged Material and Mine Tailings. Springer-Verlag, Berlin, pp. 24–43.

Fontana, S., Wahsha, M., Bini, C. (2010) - Preliminary observations on heavy metal contamination in soils and plants of an abandoned mine in Imperina Valley (Italy). Agrochimica, LIV, 4, 218-231.

Forel B., Monna F., Petit C., Bruguier O., Losno R., Fluck P., Begeot C., Richard H., Bichet V., Chateau C. (2010) – Historical mining and smelting in the Vosges Mountains (France) recorded in two ombrotrophic peat bogs. J. Geochem. Explor., 107, 9-20.

Forth, H.D. and Turk, L.M. (1972) – Soil genesis and the soil survey. In: Fundamentals of Soil Science. J. Wiley & Sons, London, pp. 203-235.

Francovich, R. (1985) – Un villaggio di minatori e fonditori di metallo nella Toscana del Medio Evo: San Silvestro (Campiglia Marittima). Archeologia Medievale, XII, 313-401.

Frau, F. and Ardau, C. (2003) – Geochemical controls on arsenic distribution in the Baccu Loci stream catchment (Sardinia, Italy) affected by past mining. Appl. Geochem., 18, 1373-1386.

Frau, F., Ardau, C., Fanfani, L. (2009) – Environmental geochemistry and mineralogy of lead at the old mine area of Baccu Locci (SE Sardinia, Italy). J. Geochem. Explor., 100, 105-115.

Gemici, U., Tarcan, G., Melis Somay, A., Akar, T. (2009) – Factors controlling the element distribution in farming soils and water around the abandoned halikoy mercury mine (Beydag, Turkey). Appl. Geochem., 24, 1908-1917.

Ghorbel, M., Munoz, M., Courjault-Rade’, P., Destrigneville C., Parseval, P., Souissi R., Souissi, F., Ben Mammou A., Abdeljaouad, S. (2010) – Health risk assessment for human exposure by direct ingestion of Pb, Cd, Zn bearing dust in the former miners’village of Jebel Ressas (NE Tunisia). Eur. J. Miner., 22, 639-649.

Gianelli, G. and Puxeddu, M. (1978) – Some observations on the age and genesis of the sulphide deposits within the Boccheggiano Group (Southern Tuscany). Mem Soc. Geol. It., 19, 705-711.

Gonzales-Fernandez, O., Jurado-Roldan, A.M., Queralt, I. (2011) – Geochemical and mineralogical features of overbank and stream sediments in the Beal Wadi (Cartagena- La Union mine district, Spain). Relation to former lead-zinc mining activities and its environmental risk. Water, Air & Soil Pollution, 215, 55-65.

Harden, J. (1982) – A quantitative index of soil development from field description: examples from a chronosequence in Central California. Geoderma, 28, 15-27.

Heikkinen, P.M. and Raisanen, M.L. (2009) – Trace metal and As solid-phase speciation in sulphide mine tailings – Indicators of spatial distribution of sulphide oxidation in active tailings impoundments. Appl. Geochem., 24, 1224-1237.

Heimann, R.B., Kreher, U., Oexle, J., Hirsekorn, V., Ullrich, O., Janke, D., Lychatz, B., Ullrich, B., Lindner, H., Wagenbreth, B. (1998) - Archaeometallurgical investigations into the iron production technology in Upper Lusatia, Saxony, From the Early Iron Age (Billendorf Period) to the 12th century AD. European Journal of Mineralogy 10, 1015–1035.

Helios-Rybicka, E. (1996) – Impact of mining and metallurgical industries on the environment in Poland. Appl. Geochem., 11, (1-2), 3-11.

ICOMANTH (2005). International Committee on Anthrosols. Circular Letter n° 5.

Jabiol, B., Brethes, A., Ponge, J.F., Toutain, F., Brun, J.J. (2007) – L’humus sous toutes ses formes. (2th edit). BIalec, Nancy, p.67.

Jambor, J.L. (1994) – Mineralogy of sulphide-rich tailings and their oxidation products. In: Jambor, J.L. and Blowes, D.W. (Eds), Environmental Geochemistry of Sulphide Mine Wastes. Miner. Ass. Can. Short Course, 22, 59-102.

Jarup, L. (2003) - Hazards of Heavy Metal Contamination. British Medical Bulletin, Vol.68: 168-182.

Jenny, H. (1941) – Factors of soil formation. McGraw-Hill, N.Y.

Jenny, H. (1980) – The soil resource. Springer Verlag, N.Y.

Kabata-Pendias, A. & Pendias, H. (2001) – Trace elements in soils and plants. 3th ed, CRC Press, Boca Raton, pp. 124-350.

Kabata-Pendias, A. (2004) - Soil-plant transfer of trace elements. An environmental issue. Geoderma 122, 143-149.

Krzaklewski, W., Barszcz, J., Malek, S., Koziol, M., Pietrzikowski, M. (2004) – Contamination of forest soils in the vicinity of the sedimentation pond after zinc and lead ore flotation in the region of Olkultz, Southern Poland. Water, Air & Soil Pollution, 159, 151-164.

Lattanzi, P., Tanelli, G. (1981) – Alcune considerazioni sulla genesi dei giacimenti a pirite della Maremma Toscana. Mem. Soc. Geol. It., 22. 159-164.

Lattanzi, P.F., Benvenuti, M., Costagliola, P., Tanelli, G. (1994) – An overview on recent research on the metallogeny of Tuscany, with special reference to the Apuane Alps. Mem Soc. Geol. Ital., 48, 613-625.

Leita, L., De Nobili, M., Pardini, G., Ferrari, F., Sequi, P. (1988) – Anomalous contents of heavy metals in soils and vegetation of a mine area in SW Sardinia, Italy. Water, Air & Soil Pollution, 48, (3-4), 423-433.

Lindsay, M.B.J., Condon, P.D., Jambor, J.L., Lear, K.G., Blowes, D.W., Ptacer, C.J. (2009) – Mineralogical, geochemical and microbial investigation of a sulphide-rich tailings deposit characterized by neutral drainage. Applied Geochemistry, 24, 2212, 2221.

Madejon, P., Murillo, J.M., Maranon, T., Cabrera, F., Lopez, R. (2002) – Bioaccumulation of As, Cd, Cu, Fe and Pb in ild grasses affected by the Aznalcollar mine spill (SW Spain). Sci. Total Environ., 290, 105-120.

Manasse, A., Mellini, M., 2002. Chemical and textural characterisation of medieval slags from the Massa Marittima smelting sites (Tuscany, Italy). Journal of Cultural Heritage 3, 187–198.

Manasse, A., Mellini, M., Viti, C., 2001. The copper slags of the Capattoli Valley, Campiglia Marittima, Italy. European Journal of Mineralogy 13, 949–960.

Marchiol, L., Fellet, G., Poscic, F., Zerbi, G. (2010) – A decade of research on phytoremediation in NE Italy: lessons learned and future directions. In: I.A. Gobulev (Ed.): Handbook of Phytoremediation. Novapublisher, N.Y. (in press).

Mascaro, I., Benvenuti, M., Corsini, F., Costagliola, P., Lascialfari, S., Vaselli, O., Tanelli, G., Bini, C., Gonnelli, C., Gabbrielli, R., Lattanzi, P. (2001b) - Heavy meta pollution of soils and plants at the Bottino Pb (Ag)-Zn mine of Bottino, Tuscany, (Italy). In: R. Cidu (ed.): Water-Rock Interaction, 1253-1256.

Mascaro, I., Benvenuti, M., Corsini, F., Costagliola, P., Lattanzi, P., Parrini, P., Tanelli, G. (2001a) – Mine wastes at the polymetallic deposit f Fenice Capanne (southern Tuscany, Italy). Mineralogy, geochemistry and environmental impact. Environ. Geol., 41, 417-429.

Mascaro, I., Benvenuti, M., Bini, C., Corsini, F., Costagliola, P., Da Pelo, S., Ferrari, M., Gabbrielli, R., Gonnelli, C., Lattanzi, P., Maineri, C., Parrini, P., Tanelli, G., Vitiello, G., (2000) – Studio ambientale dell’area mineraria dimessa del Bottino (Alpi Apuane – Toscana Settentrionale). Geologia Tecnica ed Ambientale, 2, 3-12.

Mascaro, I., Benvenuti, M., Corsini, F., Costagliola, P., Ferrari, C., Parrini, P., Tanelli, G., Da Pelo S., Lattanzi P. (1999) – Environmental study of waste dumps at the Pb-Ag Bottino mine, Apuane Alps, Italy. In: Armannsson (ed), Geochemistry of the Earth’s Surface, Balkema, Rotterdam, 203-206.

Mascaro, I., Benvenuti, M., Tanelli, G. (1995) - Mineralogy applied to archaeometallurgy: an investigation of medieval slags from Rocca San Silvestro (Campiglia M.ma, Tucany). Science and Technology for Cultural Heritage 4, 87–98.

McGrath, S.P. (1995) – Behaviour of trace elements in terrestrial ecosystems. In: R. Prost, (edit.) Contaminated soils. INRA, Paris, 35-54.

McKnight, D.M., Kimball, B.A., Bencala, K.E.(1988) – Iron photoreduction and oxidation in an acidic mountain stream. Science, 240, 637-640.

Mendez, M.O., Maier, R.M. (2008) – Phytoremediation of mine tailings in temperate and arid environments. Rev. Environ. Sci. Biotechnol., 7, 47-59.


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