Contemporary Problems of Social Work Современные проблемы социальной работы academic journal



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169
VOLUME 2, No. 1, 2016
Table 8
The Coefficients Exceeding Background Concentrations 
of Mobile Forms of Heavy Metals in the Study Area
Indicator
1
st
 zone
2
nd
 zone
3
rd
 zone
Pb
3,07
4,21
3,64
Cd
2,19
4,50
2,64
Cu
2,80
0,80
1,80
Zn
1,06
1,14
0,89
Ni
1,46
1,36
1,18
Mn
1,10
1,08
1,15
Cr
1,10
0,36
0,36
Fe
3,19
1,16
0,76
Z
c
8,97
6,61
5,42
Analysis of mobile forms of metals in soils agro area showed that the most contaminated Cu, 
Zn, Cr and Fe was the first zone; Pb, Cd, Mn – 2
nd
 zone; Ni – Zone 3 (Table 9).
Table 9
Average Content of Mobile Forms of Heavy Metals 
in the Soil of Industrial and Agro-Industrial Gardens Area
Mg/Kg*
Indicator
1
st
 zone
2
nd
 zone
3
rd
 zone
MPC
Background 
content
Pb
0,36±0,01
0,69±0,03
0,39±0,02
1,02±0,13
0,27±0,02
1,04±0,06
6,0
0,14±0,02
Cd
0,050±0,001
0,077±0,008
0,063±0,005
0,081±0,001
0,055±0,002
0,097±0,004
-
0,036±0,009
Cu
0,19±0,01
0,23±0,01
0,16±0,01
0,23±0,03
0,17±0,02
0,18±0,02
3,0
0,05±0,02
Zn
1,99±0,34
3,47±0,58
0,46±0,01
6,72±0,78
0,39±0,01
5,58±0,44
23
0,36±0,04
Ni
0,80±0,01
1,15±0,01
0,60±0,03
0,84±0,02
0,86±0,02
0,64±0,01
4,0
0,61±0,06
Mn
35,3±2,6
67,9±4,5
56,8±4,9
98,3±0,6
49,5±3,8
109,3±1,0
140
60,8±11,2
Cr
0,66±0,01
0,48±0,01
0,54±0,01
0,61±0,01
0,47±0,03
0,52±0,02
6,0
0,50±0,12
Fe
6,36±0,94
6,94±0,37
1,62±0,20
1,33±0,09
2,39±0,20
1,38±0,07
-
1,93±0,24
* In numerator – soil production sites; the denominator – gardens.
Picture 2 shows the average content of mobile forms of heavy metals in soil, sampled from 
the production areas.
The average content of mobile forms of the investigated elements in soil gardens above 
the average concentrations of these metals in the soil of industrial areas – on the Ni and Cu 
in 1,2 times; Cd 1,5 times; Mn 2,0 times; Pb 2,7 times; Zn 5,5 times. Perhaps this is due to the 
uncontrolled application of mineral and organic fertilizer to the soil of private farms residents, 
which could adversely affect the quality of the grown crop production.


170
CONTEMPORARY PROBLEMS OF SOCIAL WORK
Concentration, m
g/kg 
Picture 2.
 The Average Content of Mobile Forms of Heavy Metals in the Soil of Industrial Sites
As the data in the literature review, the most negative effect both on the productivity, and the 
chemical composition of the plant have movable mold heavy metals. The total contamination of 
the soil is characterized by a gross amount of heavy metals, the availability of components for the 
plants is determined by their mobile forms. Therefore, the content in the soil of the mobile forms 
of heavy metals – the most important indicator of the sanitary-hygienic situation in the given 
territory. [1; 2; 7; 9]
The results of the studies show a very large share of mobile forms of Cd and Mn in all the 
studied areas, which primarily may be due to high technological forms part of the movable 
elements (Table 10).
Table 10
The Content of Mobile Forms of Heavy Metals, As a% Of Gross
Indicator
1
st
 zone
2
nd
 zone
3
rd
 zone
Pb
3,8
5,6
5,3
Cd
29,3
81
47,5
Cu
0,6
0,2
0,4
Zn
0,9
0,9
0,7
Ni
1,4
1,4
1,2
Mn
12,4
13,9
14,6
Cr
0,7
0,2
0,2
Fe
0,02
0,007
0,005
The vegetables produced with gardens, and milk, taken in the private sector, measured 
normalized elements – Pb and Cd, regional pollutants – of Ni, Cr and Cu, Zn, Mn and Fe.
These data suggest that of the investigated products, according to the average content of 
the studied elements is secure by Cr – potatoes in all areas of the research; cabbage in the first 
zone; carrots in the third zone (Table 11).
Chrome, obviously, is a regional pollutant vegetables. According to calculations, 20 carrot 
samples, 80 – potatoes, 10 – 260 beet studied contain Cr in concentrations exceeding the MPC 
(Table 12).


171
VOLUME 2, No. 1, 2016
Among other elements exceeded maximum permissible concentrations of Cd in 10 potato samples, 
20 samples of beet; Zn by 10 samples beet; for Pb and Ni samples exceedance is not detected.
Table 11
Average Heavy Metal Content in Some Types of Plant Material Selected in Home Gardens, Mg/Kg
Crop
Pb
Cd
Cu
Zn
Ni
Cr
Mn
Fe
MPC, mgг/kg
0,5
0,03
5,0
10,0
0,5
0,2
-
50,0
1
st
 zone
Carrot
0,056±0,002 0,011±0,002 0,63±0,06 2,29±0,24 0,160±0,007 0,129±0,013 3,65±0,40
7,73±0,05
Potatoes 0,016±0,001 0,011±0,003 0,41±0,04 2,10±0,05 0,162±0,014 0,341±0,006 1,13±0,15 11,10±0,59
Beet
0,055±0,007 0,024±0,005 0,62±0,04 3,88±0,09 0,144±0,009 0,127±0,005 0,83±0,07
4,21±0,05
Cabbage 0,103±0,017 0,005±0,001 1,01±0,11 5,60±0,15 0,493±0,064 0,269±0,039 2,12±0,17
9,56±0,92
2
nd
 zone
Carrot
0,097±0,011 0,008±0,001 0,46±0,06 1,69±0,17 0,109±0,009 0,144±0,011 2,10±0,51
7,96±0,36
Potatoes 0,013±0,002 0,017±0,003 0,45±0,05 1,99±0,12 0,235±0,028 0,285±0,008 1,18±0,15 10,09±0,63
Beet
0,072±0,006 0,014±0,002 0,73±0,05 4,42±0,31 0,096±0,008 0,173±0,011 3,90±0,60
7,11±0,47
Cabbage 0,080±0,015 0,002±0,001 0,39±0,05 4,59±0,14 0,075±0,008 0,113±0,021 0,79±0,07
5,91±0,59
3
rd
 zone
Carrot
0,044±0,008 0,009±0,001 0,45±0,02 1,29±0,11 0,166±0,006 0,219±0,019 5,02±0,38
7,61±0,17
Potatoes 0,118±0,043 0,010±0,002 0,39±0,02 2,13±0,15 0,200±0,025 0,283±0,012 1,29±0,11 10,66±0,36
Beet
0,090±0,005 0,025±0,003 0,63±0,07 8,66±1,27 0,159±0,008 0,160±0,004 0,85±0,06
5,88±0,60
Note: «–» – there are no regulations.
Table 12
The Content of Heavy Metals in Products of Plant Origin
Сrop
Content of metal, mg/kg
The num-
ber of 
samples 
exceed-
ing the 
MPC
The 
aver-
age 
rate 
of ex-
cess
The distribution of samples per 
band of MPL, %
average
minimal
maximal
<0,10 0,11-
0,25
0,26-
0,50
0,51-
0,75
0,76-
1,00
Lead
Carrot
0,067±0,004 0,013±0,003 0,136±0,040
0
-
37,5
50,0
12,5
-
-
Potatoes 0,053±0,012 0,002±0,001 0,340±0,069
0
-
87,5
-
12,5
-
-
Beet
0,074±0,003 0,034±0,005 0,112±0,028
0
-
25,0
75,0
-
-
-
Cadmium
Carrot
0,010±0,001 0,005±0,001 0,017±0,004
0
-
-
50
37,5
12,5
-
Potatoes 0,013±0,001 0,003±0,001 0,030±0,009
10
1,01
-
25,0
50,0
-
-
Beet
0,021±0,001 0,005±0,001 0,042±0,008
20
1,31
-
12,5
37,5
12,5
12,5
Zinc
Carrot
1,69±0,08
0,74±0,10
2,97±0,53
0
-
12,5
62,5
12,5
-
-
Potatoes
2,07±0,05
1,41±0,11
2,75±0,39
0
-
-
75,0
25,0
-
-
Beet
5,88±0,41
3,08±0,96
14,39±1,47
10
1,44
-
-
62,5
12,5
12,5
Nickel
Carrot
0,143±0,004 0,065±0,009 0,184±0,030
0
-
-
25,0
62,5
-
-
Potatoes 0,203±0,010 0,081±0,007 0,373±0,036
0
-
-
25,0
50,0
25,0
-
Beet
0,131±0,004 0,059±0,008 0,201±0,023
0
-
-
50,0
50,0
-
-
Chromium
Carrot
0,168±0,007 0,095±0,009 0,308±0,053
20
1,30
-
-
12,5
37,5
25,5
Potatoes 0,298±0,004 0,235±0,051 0,349±0,033
80
1,49
-
-
-
-
-
Beet
0,156±0,003 0,124±0,014 0,224±0,030
10
1,12
-
-
-
50,0
37,5


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