46
or to achieve 10 ng/L MIB in finished water:
PAC Dose (mg/L) = 10.8 x ln(MIB
raw
) – 24.8
Equation 5.6
Where the raw (MIB
raw
) and finished (MIB
finished
) water MIB concentrations are in ng/L.
For example, if the influent MIB concentration is 30 ng/L and the desired effluent MIB
concentration is 10 ng/L, a 20B PAC dose of about 11.9 ng/L would be required using
the equation and 13.5 ng/L using the nomograph. Practical operating curves were
generated for future use of Norit 20B by all COP WTPs. The operating curves are easy-
to-use nomographs that can be used instead of Equations 5.5 and 5.6, although the
equations are more accurate than reading from the nomograph.
Slurry storage of Norit 20B PAC at a full-scale WTP for approximately six-months did not
effect its removal efficiency for MIB in raw water. However, ordering and storage of PAC
is critical for effective MIB removal. On-site PAC storage should be based upon
maximum PAC feed rates, maximum design WTP flowrate, and deliveries every five to
seven days. A schedule of PAC deliveries should be prepared and provided to PAC
suppliers at least one month in advance. PAC feed facilities should be designed to
handle 40 to 50 mg/L of PAC.
PAC doses should vary with flowrate and approximately weekly, based on GC/MS
analysis of MIB and geosmin concentrations in raw and finished water. Alternatively
FPA can be used more frequently to adjust PAC dosages. However, weekly
confirmation by GC/MS should be included. Costs for PAC may exceed $25,000 per
week during MIB pulses (assuming 15 mg/L, 100 MGD, $0.30/lb PAC). Therefore
conducting GC/MS analysis for MIB of raw and finished water to optimize PAC dose
(Equation 5.6) can be extremely cost effective. It is critical that the analytical laboratories
know in advance of the MIB/geosmin sampling and the need for rapid (1 to 2 day)
turnaround of the data. All WTPs within a city should be sampled and analyzed on the
same day (e.g., Monday) and PAC doses adjusted accordingly within two days (e.g.,
Wednesday), see Figure 3-1.
5.5.3 Activated Carbon Filter Caps
GAC capped filters operated in an adsorption or biologically active mode will remove
some MIB and geosmin. Existing anthracite filter caps could be replaced by GAC caps
where MIB and geosmin removal is desired. The GAC caps should be 30 to 50 inches in
depth. The point of chlorination should be after filtration to encourage biofiltration, which
could affect CT disinfection credits. Depending upon operating conditions 20% to > 90%
MIB and geosmin removal can be achieved (Figure 5-11).
PAC addition may not be
required when operating in adsorption modes only, while it would be required under
biologically active modes (exhausted adsorption capacity). GAC caps operated under
adsorption mode, and to a lesser extent under a biodegradation mode, would provide
TOC removal and removal of synthetic compounds (e.g., estrogenic compounds and
47
pharmaceuticals). WTPs with short presedimentation contact times for PAC and/or high
influent T&O concentration would benefit most by GAC filter caps. GAC filter caps add
another layer of treatment in a multiple-barrier approach to T&O control.
Figure 5-11. Breakthrough of MIB (upper) and geosmin (lower) in laboratory biofilters (from Malcolm Pirnie
Inc. report to the City of Chandler).
48
5.5.4 Advanced Oxidation
Ozone and UV irradiation can be effective at removing MIB and geosmin. Ozone
dosages capable of
Giardia and
Cryptosporidium inactivation (2 to 4 mg/L) are capable
of 80% to > 95% oxidation of MIB and geosmin in CAP or SRP water. Ozone dosages
of 2 to 4 mg/L will form bromate, and depending upon the initial bromide concentration in
the raw water (80 to 150
µ
g/L), bromate concentrations approaching the MCL of 10
µ
g/L
would be formed. Therefore, acid and/or ammonia addition
prior to ozonation would be
required. However, if ozone was used primarily for T&O control, lower ozone dosages
(e.g., 0.75 mg/L) could achieve significant MIB removal (e.g., 60% to 80%).
UV irradiation dosages required for MIB or geosmin oxidation are approximately 100
times greater than dosages used for microbial inactivation. Therefore, UV-irradiation
probably is not cost-effective.
49
SECTION 6
PROGRAM ASSESSMENT
6.1 CONTINUOUS EVALUATION AND COMMUNICATIONS
6.1.1 Rationale
One of the keystone concepts of the T&O management program is rapid response. It is
now possible to collect and analyze water samples within 2-3 days, allowing week-by-
week evaluation of the T&O situation. This makes it possible to respond quickly,
implementing one or more control measures as needed.
6.1.2 Implementation
A T&O Newsletter was developed for this purpose. Section 3 discusses the rationale
and goals of the Newsletter. The T&O Newsletter should be written and distributed
weekly during the T&O season, roughly June through October. As a minimum, the
Newsletter should contain the latest sampling data and recommendations for PAC
dosing and other implementation measures. The format should be consistent from
week to week, to make it easy for COP staff to find important information quickly.
Electronic distribution via email attachment has worked very well. COP should
encourage technical staff to utilize the T&O Newsletter to share observations, treatment
concepts, water delivery forecasts, and other ideas with WSD staff.
6.2 ANNUAL (END OF YEAR) EVALUATION
6.2.1 Rationale
The T&O management program should continuously improve in the face of changing
circumstances. Accomplishing this requires continuous evaluation of the program as it
evolves. Thoughtful technical evaluation can document success, which can improve the
public image of the WSD and improve staff morale, but is also needed to identify
weaknesses. An annual evaluation could also be used to justify the cost of new
facilities and equipment needed to improve the quality of water delivered to consumers.
6.2.2 Elements of the Annual Evaluation
The annual evaluation should include an evaluation of the quality of water delivered to
customers each year, a review of operational issues, and an analysis of economic and
institutional issues.