Ph o to v o l t a i c s I n te r n at i o n a l
53
Cell
Processing
For more complicated (arbitrary) layouts,
SERIS has developed its own software
called GRIDDLER [10]. This software can
import metal grid patterns from images
and perform a meshing and a subsequent
finite element analysis, for determining (for
example)
the percentage of
R
s
of the solar
cell stemming from (1) the grid itself, (2)
emitter lateral series resistance, (3) back-
surface field lateral series resistance, and
(4) bulk series resistance. Furthermore,
a p er turbation analysis allows the
determination of
how the grid patterns can
be changed with the aim of attaining their
optimum layouts.
Fill factor loss analysis
Taking the measured
R
s
and
R
sh
under
maximum power conditions of the solar
cell as input parameters, an advanced
FF
loss analysis [8]
can be performed
by desc r ibing the c u r rent–volt age
characteristics of the solar cell via the
two-diode model shown in Fig. 10. The
FF
of the solar cell is then determined
by the diode saturation currents
J
01
and
J
02
, describing ideal and non-ideal
recombination in the solar cell, as well as
by the series
and shunt resistances
R
s
and
R
sh
. To analyze
FF
losses, it is important
to determine the relative contributions of
these quantities.
An ‘upper limit’ fill factor
FF
J01
can
be calculated by assuming only bulk
recombination, in other words assuming
no non-ideal
second-diode recombination,
no series resistance and an infinite shunt
resistance. The loss in
FF
due to second-
diode recombination currents (non-ideal
recombination), and to
R
s
and
R
sh
, can
then be calculated [8]. This is illustrated
in Fig. 11 for the standard industrial
p-type Al-BSF solar cell of Fig. 6. It is
clear that
R
s
is
the biggest contributor
to the
FF
loss of this cell. However,
for more advanced, higher-efficiency
solar cells the contribution of the
J
02
component becomes larger. For such cells
it is extremely important to know the root
cause of the
FF
losses
in order to devise the
optimal strategy for improvement.
“
The loss quantification
method enables the largest root
causes of poor cell performance
to be focused on first, before
‘turning knobs’ to fine-tune
secondary effects.
”
Conclusion
As remarked by Lord Kelvin 140 years ago,
“To measure is to know.” In
this paper it
has been shown that current, voltage and
fill factor losses for silicon wafer solar cells
can be fully quantified by a combination of
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